Dichloromethane

Effective Solvent Properties: Dichloromethane exhibits high miscibility with numerous organic solvents, enhancing its adaptability across various industrial uses.

Non-Flammable Characteristic: Its non-flammable nature significantly improves operational safety during handling and application in manufacturing and processing.

Strong Performance in Paint Removal and Cleaning: Owing to its powerful solvent capabilities, dichloromethane is widely employed in paint stripping and industrial cleaning operations.

High Volatility: The compound’s volatile properties facilitate efficient extraction and separation processes, rendering it particularly useful in chemical manufacturing.


Product Details

Dichloromethane, commonly referred to as methylene chloride, is a chlorinated hydrocarbon derived from methane by substituting two hydrogen atoms with chlorine atoms, resulting in the chemical formula CH₂Cl₂. It is a colorless, transparent liquid that is denser than water and emits a faint, sweet aroma reminiscent of ether. Although dichloromethane itself is non-flammable, it can form explosively combustible mixtures in highly oxygenated environments. The compound has limited solubility in water but demonstrates miscibility with numerous organic solvents—including chlorinated compounds, ethers, ethanol, and N,N-dimethylformamide—in all proportions. Owing to its high volatility and strong solvent power, it is extensively utilized in applications such as paint removal, industrial cleaning, and chemical extraction processes.


Dichloromethane


Parameters

Melting point 

-97 °C

Boiling point 

39.8-40 °C mm Hg(lit.)

density 

1.325 g/mL at 25 °C(lit.)

vapor density 

2.9 (vs air)

vapor pressure 

24.45 psi ( 55 °C)

refractive index 

n20/D 1.424(lit.)

Fp 

39-40°C

storage temp

room temp

solubility 

Miscible in ethyl acetate, alcohol, hexanes, methanol, diethyl ether, n-octanol,

acetone benzene, carbon tetrachloride, diethyl ether and chloroform.

form 

Liquid

color 

APHA: ≤10

Specific Gravity

1.329 (20/20℃)

Odor

Odor threshold 160 to 230 ppm

PH

7 (20°C)

Odor Threshold

160ppm

explosive limit

13-22%(V)

Water Solubility 

20 g/L (20 ºC)

λmax

λ: 235 nm Amax: 1.00
λ: 240 nm Amax: 0.20
λ: 250 nm Amax: 0.05
λ: 260 nm Amax: 0.02
λ: 340-400 nm Amax: 0.01

Merck 

14,6063

BRN 

1730800

Henry's Law Constant

2.49 at 30 °C (headspace-GC, Sanz et al., 1997)

Dielectric constant

9.1(20℃)

Exposure limits

TLV-TWA 50 ppm (~175 mg/m3) (ACGIH); carcinogenicity: Suspected Human

Carcinogen (ACGIH), Animal Sufficient Evidence, Human Inadequate Evidence

(IARC).

Stability:

Volatile

LogP

1.250

Surface tension

26.5mN/m at 20°C

CAS DataBase Reference

75-09-2(CAS DataBase Reference)

NIST Chemistry Reference

Methylene chloride(75-09-2)

IARC

2A (Vol. Sup 7, 71, 110) 2017

EPA Substance Registry

System

Methylene chloride (75-09-2)

Absorption

in accordance

 

Safety Information

Hazard Codes 

Xn,T,F,N,C

Risk Statements 

40-39/23/24/25-23/24/25-11-67-36/37/38-68/20/21/22-20/21/22-50-37-34

Safety Statements 

23-24/25-36/37-45-16-7-26-61-36/37/39

RIDADR 

UN 1593 6.1/PG 3

WGK Germany 

2

RTECS 

PA8050000

3-10

Autoignition Temperature

556 °C

Hazard Note 

Harmful

TSCA 

Yes

HS Code 

2903 12 00

HazardClass 

6.1

PackingGroup 

III

Hazardous Substances Data

75-09-2(Hazardous Substances Data)

Toxicity

LD50 orally in young adult rats: 1.6 ml/kg (Kimura)

IDLA

2,300 ppm

 

Dichloromethane

 

Dichloromethane is valued for its high solvency and comparatively low toxicity. It finds widespread application in the manufacture of safety films and polycarbonates. It is also employed as a solvent in coatings, a degreasing agent for metals, a propellant in aerosols, a blowing agent for polyurethane foam, a mold release agent, and an effective paint remover. In the pharmaceutical sector, this colorless liquid is used as a reaction medium, notably in the production of antibiotics such as ampicillin, hydroxybenzyl penicillin, and cephalosporins. Additional uses include serving as a solvent in film processing, a dewaxing agent in petroleum refining, an extractant in organic synthesis, a foaming agent for various foam plastics including polyurethane, and as a cleaning agent for metallic surfaces.



Dichloromethane




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