Xylene
Solvent Efficiency: Xylene functions as an effective organic solvent with complete miscibility in ethanol, chloroform, and diethyl ether, supporting applications in coating formulations, polymer resins, adhesive systems, and pharmaceutical manufacturing.
Thermal Properties: Characterized by a boiling range of 137-140°C, it maintains stability for thermally sensitive processes while providing sufficient volatility for rapid solvent evaporation when required.
Isomeric Forms and Applications: Comprises three structural isomers (ortho-, meta-, para-xylene) with distinct industrial utilities, including polyester synthesis and manufactured fiber production.
Toxicological Profile and Safety: Exhibits moderate toxicity with potential carcinogenic properties, necessitating strict exposure controls (TWA 100 ppm) and protective measures in occupational settings.
Xylene (systematically named dimethylbenzene) is a colorless, transparent aromatic hydrocarbon liquid formed through the substitution of two hydrogen atoms on a benzene ring with methyl functional groups. This compound demonstrates a characteristic boiling point range of 137-140°C. The structural configuration gives rise to three isomeric variations determined by the relative positioning of the methyl substituents: ortho-xylene (1,2-dimethylbenzene), meta-xylene (1,3-dimethylbenzene), and para-xylene (1,4-dimethylbenzene). In industrial contexts, the term "xylene" typically refers to a commercial mixture comprising these three structural isomers along with varying proportions of ethylbenzene. Commercial specifications are generally categorized as premium or first-grade quality, with purified batches demonstrating controlled distillation ranges of either 3°C or 5°C according to established chemical industry standards.
Parameters
Melting point | -34 °C |
Boiling point | 137-140 °C (lit.) |
density | 0.86 g/mL at 25 °C (lit.) |
vapor density | 3.7 (vs air) |
vapor pressure | 18 mm Hg ( 37.7 °C) |
refractive index | n20/D 1.497(lit.) |
Fp | 77 °F(lit.) |
storage temp. | Flammables area |
solubility | Chloroform (Soluble), Methanol (Slightly) |
form | Liquid |
color | APHA: ≤10 |
Odor | char. sweet odor |
explosive limit | 7% |
Water Solubility | <0.1 g/L (20 ºC) |
Merck | 14,10081 |
BRN | 1901563 |
Exposure limits | ACGIH: TWA 100 ppm; STEL 150 ppm |
Dielectric constant | 10.0(Ambient) |
Stability: | Volatile, flammable and its vapors form explosive mixtures with air at room temperature. |
InChIKey | KAKOUNRRKSHVJO-UHFFFAOYSA-N |
LogP | 3.16 at 20℃ |
CAS DataBase Reference | 1330-20-7(CAS DataBase Reference) |
IARC | 3 (Vol. 47, 71) 1999 |
EPA Substance Registry System | Xylene (1330-20-7) |
Safety Information
Hazard Codes | Xn,F |
Risk Statements | 10-20/21-38-36/38-65-48/20 |
Safety Statements | 25-36/37-62 |
RIDADR | UN 1307 3/PG 3 |
OEB | A |
OEL | TWA: 100.0 ppm; 435.0 mg/m3, STEL: 150.0 ppm; 655.0 mg/m3 |
WGK Germany | 2 |
RTECS | ZE2100000 |
Autoignition Temperature | 867 °F |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | II |
HS Code | 29024400 |
Hazardous Substances Data | 1330-20-7(Hazardous Substances Data) |
Toxicity | LD50 oral in rat: 4300mg/kg |
Xylene demonstrates complete miscibility with ethanol, chloroform, and diethyl ether while being immiscible with aqueous systems. This compound serves extensively as an organic solvent in pharmaceutical synthesis, coating formulations, polymer resins, dye manufacturing, explosive production, and agrochemical preparations. The substance presents moderate toxicity with documented carcinogenic potential. Environmental contamination primarily stems from synthetic fiber production, plastic manufacturing, fuel processing, rubber commodities, coating additives, adhesive formulations, waterproofing materials, in addition to combustion emissions from hydrocarbon fuels and tobacco smoke. Regulatory frameworks govern its industrial applications to mitigate ecological and health impacts.






